bokomslag Molecular Conformation and Organic Photochemistry
Vetenskap & teknik

Molecular Conformation and Organic Photochemistry

Rasmus Y Brogaard

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  • 124 sidor
  • 2014
Rasmus Brogaard's thesis digs into the fundamental issue of how the shape of a molecule relates to its photochemical reactivity. This relation is drastically different from that of ground-state chemistry, since lifetimes of excited states are often comparable to or even shorter than the time scales of conformational changes. Combining theoretical and experimental efforts in femto-second time-resolved photoionization Rasmus Brogaard finds that a requirement for an efficient photochemical reaction is the prearrangement of the constituents in a reactive conformation. Furthermore, he is able to show that by exploiting a strong ionic interaction between two chromophores, a coherent molecular motion can be induced and probed in real-time. This way of using bichromophoric interactions provides a promising strategy for future research on conformational dynamics.
  • Författare: Rasmus Y Brogaard
  • Format: Pocket/Paperback
  • ISBN: 9783642426742
  • Språk: Engelska
  • Antal sidor: 124
  • Utgivningsdatum: 2014-06-11
  • Förlag: Springer-Verlag Berlin and Heidelberg GmbH & Co. K