Oxide-Ion Conduction in the Dion-Jacobson-Type Layered Perovskites

This book reports a study of a class of Dion-Jacobson-type layered perovskite oxides in which high oxide-ion conductivities in phases were discovered for the first time in the world. The oxide-ion conductors are important in various energy conversion devices and environmental protection applications such as solid-oxide fuel cells, oxygen gas sensors, oxygen separation membranes, and oxygen-based catalysts. The discoveries are based on a new screening method, called the bond valence method, combined with an original design concept. The present finding of high oxide-ion conductivity reported in the thesis suggested the potential of Dion-Jacobson phases as a platform to identify superior oxide-ion conductors. To understand what causes such high oxide-ion conductivities in these layered perovskite oxides, the author analyzed their crystal structures at high temperature and described the relationship between oxide-ion conductivities and their crystal structures. A deep understanding of the mechanisms of oxide-ion diffusivity at an atomic level in the Dion-Jacobson phases is clarified. The discovery of these materials, the new screening method, and the original design concept make possible the realization of many environment-friendly technologies. The findings in this thesis facilitate the possibilities for many novel applications that will help lead to a sustainable future.