Basics of Analytical Chemistry and Chemical Equilibria

A Quantitative Approach

Häftad, Engelska, 2023

Av Brian M. Tissue, USA) Tissue, Brian M. (Virginia Tech, Blacksburg, VA

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BASICS OF ANALYTICAL CHEMISTRY AND CHEMICAL EQUILIBRIA Familiarize yourself with the fundamentals of analytical chemistry with this easy-to-follow textbook Analytical chemistry is the study of chemical composition, concerned with analyzing materials to discover their constituent substances, the amounts in which these substances are present, and more. Since materials exist in different states and undergo reactions, analytical chemistry is also concerned with chemical equilibria, the state at which various reactants and substances will undergo no observable chemical change without outside stimulus. This field has an immense range of practical applications in both industry and research and is a highly desirable area of expertise for the next generation of chemists. Basics of Analytical Chemistry and Chemical Equilibria provides an introduction to this foundational subject, ideal for specialized courses. It introduces not only the core concepts of analytical chemistry but cultivates mastery of various instrumental methods by which students and researchers can undertake their own analyses. Now updated to include the latest research and expanded coverage, Basics of Analytical Chemistry and Chemical Equilibria promises to situate a new generation of readers in this growing field. Readers of the second edition of Basics of Analytical Chemistry and Chemical Equilibria will also find: A new chapter on structure determinationRevised and expanded descriptions of chemical instrumentation‘You-try-it’ exercises throughout to further develop practical student knowledgeCompannion website of associated materials including end-of-chapter solutions, spreadsheets for student use, and moreBasics of Analytical Chemistry and Chemical Equilibria is an ideal textbook for students in chemistry, biochemistry, and environmental science, as well as students in related fields, including chemical engineering and materials science, for whom analytical chemistry offers a useful toolset.

Produktinformation

Utgivningsdatum2023-02-28
Mått178 x 252 x 31 mm
Vikt816 g
FormatHäftad
SpråkEngelska
Antal sidor496
Upplaga2
FörlagJohn Wiley & Sons Inc
ISBN9781119707356

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Preface ixAbout the Companion Website xiiiI Quantitative Analysis Using Reactions That Go to “completion” 11 Making Measurements 31.1 Introduction 31.2 Glp and a Few Other Important Acronyms 101.3 Precision and Random Error 141.4 Discarding a Suspected Outlier 251.5 Calibration 281.6 Maintaining Accurate Results 44Practice Exercises 492 Sample Preparation, Extractions, and Chromatography 532.1 Sampling and Control Samples 532.2 Sample Preparation 592.3 Solvents and Solutions 652.4 Introduction to Solubility 692.5 Extraction and Partitioning Theory 722.6 Introduction to Stationary Phases 842.7 Solid-Phase Extraction (SPE) 882.8 Column Chromatography 94Practice Exercises 973 Classical Methods 1033.1 Introduction 1033.2 Review of Chemical Reactions 1053.3 Reactions in Aqueous Solution 1123.4 Gravimetry 1213.5 Titration 1253.6 Titration Curves 1333.7 Coulometry 135Practice Exercises 1384 Molecular Spectroscopy 1434.1 Introduction 1434.2 Properties of EM Radiation 1444.3 Electromagnetic Spectrum 1484.4 Spectroscopic Transitions 1504.5 UV Vis Absorption Spectroscopy 1554.6 UV Vis Instrumentation 1584.7 Beer–Lambert Law 1614.8 Molecular Fluorescence 170Practice Exercises 178II Reactions That Do Not Go to “completion.” Equilibria in Aqueous Solutions 1835 Acid–base Equilibria and Activity 1855.1 Acids and Bases 1855.2 Weak Acids and Weak Bases 1925.3 Water and Kw 1975.4 Acid Strength 2025.5 The Concept of Activity 2075.6 Acid–Base Equilibrium Calculations 219Practice Exercises 2256 Buffer Solutions and Polyprotic Acids 2296.1 Buffer Solutions 2296.2 Alpha Fraction Plots 2346.3 Weak Acid Titration Curve 2386.4 Polyprotic Acids 241Practice Exercises 2507 Metal–ligand Complexation 2537.1 Complex Terminology 2547.2 Complex Equilibria 2587.3 Competing Equilibria 2647.4 Stepwise Complexation 2717.5 Immunoassays 276Practice Exercises 2798 Precipitation Equilibria 2838.1 Precipitate Equilibrium 2848.2 Molar Solubility 2918.3 Common-Ion Effect 2978.4 Precipitation and Competing Equilibria 2998.5 Drinking Water 304Practice Exercises 306III Instrumental Methods and Analytical Separations 3119 Electroanalytical Chemistry 3139.1 Introduction 3139.2 Standard Reduction Potentials 3169.3 Using Half Reactions 3219.4 Background on Spontaneous Reactions and Equilibrium 3279.5 Reaction Energies, Voltages, and the Nernst Equation 3319.6 Electrochemical Cells 3349.7 Potentiometry 3409.8 Ion-Selective Electrodes (ISE) 3429.9 Voltammetry 350Practice Exercises 35810 Atomic Spectrometry 36110.1 Atomization 36310.2 Atomic Absorption Spectrometry (AAS) 36810.3 Atomic Emission Spectrometry (AES) 37810.4 Inductively Coupled Plasma Mass Spectrometry (ICP-MS) 38110.5 Other Mass Spectrometer Designs 390Practice Exercises 39511 Molecular Structure Determination 39911.1 Introduction 39911.2 Molecular Mass Spectrometry 40211.3 Fourier-Transform Infrared Spectroscopy 40711.4 FTIR Instrumentation 41211.5 Nuclear Magnetic Resonance Spectroscopy 41611.6 NMR Instrumentation 421Practice Exercises 42412 Analytical Separations 42512.1 Thin-Layer Chromatography 42612.2 Chromatogram Terminology 43112.3 Separation Efficiency 43512.4 Gas Chromatography (GC) 43912.5 Gas Chromatography Mass Spectrometry (GC-MS) 44412.6 High Performance Liquid Chromatography 44712.7 Electrophoresis 460Practice Exercises 464Index 469